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Josie is a psychological warfare genius whose intuition makes her invaluable in interrogation. She appears in Chuck Versus the Muuurder. She is chosen by Chuck as a candidate for the position of the next human Intersect. Casey figured they had to bring in a girl to find someone as 'feely' as Chuck.
She informed Morgan that his his pop culture questions were pointless and meaningless, and only a man would care who the 'best' James bond was. Neither Chuck nor Morgan could understand what she was saying, but Director Bentley nods in agreement.
During the murder investigation, she proves herself both manipulative and emotional under interrogation. She tells Sarah that she had been involved with her ex for six years and he left her for being too emotional, and wanted to know how Sarah got 'the Intersect' to commit.
Chuck discovered a positive pregnancy test in her bag during a search, which he deduced explained her emotional state.
Despite not being in the running for being the new Intersect, she did manage to survive the episode.