Jasmine is assigned by Vivian Volkoff to assist Riley in locating Orion's Laptop which had contained the Laptop Intersect. She is first seen at the very start of "Chuck Versus Agent X" inside a undisclosed CIA base where she distracts the guard and then knock him out. She and Riley then take some sort of tracking device which is able to track the location of the Laptop.
They track down the Laptop to a camp side where Chuck's bachelor party is being hold as Devon accidentally took the wrong bag on the trip which contained the laptop. Whilst Riley's mercenaries hunt down Chuck, Morgan, Casey and Devon Jasmine ties Jeff to a tree and begins to try to interrogate him which he mistakes for foreplay. Chuck goes back into the camp to save Jeff and ends up getting into a knife fight with Jasmine who is proficient with knives.
She is seen later (in the same episode) in Somerset, England where her, Riley and his mercenaries have tracked down the location of Agent X's house. Her team end up in a gun fight with Casey and Mrs. Winterbottom whilst Chuck and Sarah look for agent X's spy will. The Volkoff's team are winning and the team, minus Riley, go into the house to finish their enemies off but discover that Mrs. Winterbottom has rigged a grenade up which promptly blows up the house, killing everyone inside.